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Overview
Spin coating is the preferred method for application of thin,
uniform films to flat substrates. This process is very simple,
illustrated in Figure 1 at right. An excess amount of polymer
solution is placed on the substrate. The substrate is then
rotated at high speed in order to spread the fluid by centrifugal
force. Rotation is continued for some time, with fluid being
spun off the edges of the substrate, until the desired film
thickness is achieved. The solvent is usually volatile, providing
for its simultaneous evaporation.
This process is used extensively in microlithography for
the manufacture of integrated circuits. A photoresist solution
is applied to a wafer using spin coating followed by heating
to remove the solvent. The polymer itself is photochemically
active. A positive resist reacts with radiation to
become more soluble. In contrast, a negative resist
reacts with radiation to become less soluble. Thus, the use
of masked radiation followed by selective removal of the irradiated
or nonirradiated polymer provides for the establishmend of
a detailed pattern on the surface.
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Figure 1.
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